Researchers design a simple method to regulate the self-assembly of hole-selective monolayers
Researchers from Fraunhofer ISE and King Abdullah University of Science and Technology (KAUST) have designed a perovskite-silicon tandem solar cell that is said to offer improved reproducibility. The device uses self-assembled monolayers (SAMs) that reportedly result in low parasitic absorption and rapid charge extraction.
Schematic of the fully-textured perovskite/silicon tandem solar cell structure studied. Image from: small methods
SAMs have shown great potential as hole-selective contacts for high-efficiency PSCs due to their easy processing, passivation capability, and low parasitic absorption. However, for the deposition of SAMs with a monolayer thickness and a high packing density on metal oxide substrates, critical challenges persist. To address these, the study focuses on the impact of annealing temperature – an intrinsic yet so far unexplored process parameter – during the formation of SAMs.