Researchers demonstrate reversible light-induced strain in halide perovskites
Researchers at the University of California (UC Davis) and Empa have shown that single-crystal halide perovskites can reversibly change their lattice under above-bandgap light excitation and elastically return to their original structure when the light is removed. This light-driven, hysteresis-free lattice response highlights soft-lattice halide perovskites as promising candidates for light-controlled semiconductor and strain-engineered devices.
Mechanically and chemically modulated strain in monocrystalline halide perovskites (HPs) has already been shown to improve stability and phase purity, but the interplay between photoexcitation-driven lattice distortions, strong electron-phonon coupling, and A-site cation dynamics has not been fully clarified. In this study, transient lattice distortions were measured in single-crystal MAPbBr3, FAPbBr3, and CsPbBr3 in response to above-bandgap light excitation using an X-ray probe to directly monitor structural changes. The measurements reveal reversible, hysteresis-free photoinduced lattice distortion: when light is applied, the internal lattice parameters shift, and when the light is turned off, the crystals recover their initial structure, and this cycle can be repeated many times.