Perovskite diode reaches 26.7% PCE and 31% EQE in dual PV–LED operation
Researchers from the University of Science and Technology of China and the University of Colorado Boulder have demonstrated a perovskite diode that acts as both an efficient solar cell and a high‑efficiency LED using the same 800 nm thick absorber layer.
The device embeds porous micrometer‑scale alumina (Al₂O₃) “sponge” islands (∼5 μm wide, 0.5 μm tall) inside the perovskite, allowing a layer thick enough for photovoltaics to also extract light efficiently like an LED. In conventional devices, perovskite LEDs rely on ultrathin, discontinuous layers of about 50 nm, whereas efficient solar cells need layers roughly sixteen times thicker; this architecture reconciles those opposing thickness requirements in a single stack. Surface‑functionalized alumina nanoparticles assemble electrostatically into these islands: one population is coated with negatively charged Me‑4PACz, the other with positively charged ODA, giving a porous, low‑index network the perovskite can grow through without disrupting charge transport.

