Researchers at Monash University, University of Sydney and University of Melbourne in Australia have addressed a fundamental challenge standing before massive commercialization of perovskite solar cells - light-induced phase segregation, in which illumination, such as sunlight, disrupts the carefully arranged composition of elements within mixed-halide perovskites.

Light-induced segregation often leads to instability in the material’s bandgap, interfering with the wavelengths of light absorbed, while reducing charge-carrier conduction and the efficiency of devices.

Researchers have shown that high-intensity light will undo the disruption caused by light at lower intensities, and that this approach can be used to actively control the material’s bandgap.

Dr. Chris Hall, a member of Professor Trevor Smith’s team at The University of Melbourne, and Dr. Wenxin Mao of Professor Udo Bach’s group at Monash University, first noticed the potential to explore this avenue of investigation during a separate experiment.

“It was one of those unusual discoveries that you sometimes hear about in science,” Chris said. “We were performing a measurement, looking for something else, and then we came across this process that at the time seemed quite strange. However, we quickly realized it was an important observation.”

They enlisted the help of Dr. Stefano Bernardi, a member of Dr. Asaph Widmer-Cooper’s group at the University of Sydney, who led the computational modelling work to better understand their surprising solution to the issue.



Stefano said: “What we found is that as you increase the excitation intensity, the local strains in the ionic lattice, which were the original cause of segregation, start to merge together. When this happens, the local deformations that drove segregation disappear.

“On a normal sunny day, the intensity is so low that these deformations are still localized. But if you find a way to increase the excitation above a certain threshold, for example by using a solar concentrator, then segregation disappears.”

The implications of the findings are significant, with researchers now able to retain the optimal composition of elements within mixed-halide perovskites when they are exposed to light, necessary for its use in solar cells.

“A lot of people have approached this problem by investigating ways of suppressing light-induced disorder, such as looking at different compositions of the material or changing the dimensions of the material,” Chris said.

“What we’ve shown is that you can actually use the material in the state that you want to use it, for a solar cell - all you need to do is focus more light onto it.

“An exciting extension of this work is that the ability to rapidly switch the bandgap with light opens an interesting opportunity to use perovskites in data storage,” Wenxin said.

Chris added: “We’ve done the fundamental work and the next step is to put it into a device.”

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