A team of researchers, that includes researchers from the AMOLF Institute in the Netherlands and Argonne National Laboratory and is led by the University of California San Diego, has observed nanoscale changes in hybrid perovskite crystals that could offer new insights into developing low-cost, high-efficiency solar cells.

Using X-ray beams and lasers, the researchers studied how hybrid perovskites behave at the nanoscale level during operation. Their experiments revealed that when voltage is applied, ions migrate within the material, creating regions that are no longer as efficient at converting light to electricity. "Ion migration hurts the performance of the light absorbing material. Limiting it could be a key to improving the quality of these solar cells," said a member of the Sustainable Power and Energy Center at UC San Diego.

The team has shown that by using a technique called nanoprobe X-ray fluorescence, it's possible to probe deep into hybrid perovskite materials without damaging them. The researchers studied a type of hybrid perovskite called methylammonium lead bromide, which contains negatively charged bromine ions. Like other hybrid perovskites, its crystalline structure contains many vacancies, or missing atoms, which have been suspected to allow ions to move readily within the material when a voltage is applied.

The researchers first performed nanoprobe X-ray fluorescence measurements on the crystals to create high-resolution maps of the atoms inside the material. The maps revealed that when voltage is applied, the bromine ions migrate from negatively charged areas to positively charged areas.

Next, the researchers shined a laser on the crystals to measure photoluminescence (the material's ability to emit light when excited by a laser) in different areas of the crystals. A good solar cell material emits light very well, so the higher the photoluminescence, the more efficient the solar cell should be. The areas with higher bromine concentrations had up to 180% higher photoluminescence than areas depleted of bromine ions.

"We watch the bromine ions migrate within minutes and see that the resulting bromine-rich areas have the potential to become better solar cells while the performance is degraded in bromine-poor areas," the team said. The researchers are now exploring ways to limit bromine migration in methylammonium lead bromide and other hybrid perovskites. Researchers say that one potential option would be growing hybrid perovskite crystals in different conditions to minimize the number of vacancies and limit ion migration in the crystalline structure.



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