Researchers at the Georgia Institute of Technology have demonstrated a novel approach aimed at addressing perovskite’s durability problem: encasing the perovskite inside a double-layer protection system made from plastic and silica.
The research team developed a multi-step process to produce encased perovskite nanocrystals that exhibit strong resistance to degradation in moist environments.
“Perovskite nanocrystals are highly susceptible to degradation, particularly when they come into contact with water,” said Zhiqun Lin, a professor in the Georgia Tech School of Materials Science and Engineering. “This dual-shelled system offers two layers of protection while allowing each nanocrystal to remain a distinct and separate unit, achieving the maximum amount of surface area and other physical characteristics of the perovskite needed for optimizing optoelectronic applications.”
For this study, which was supported by the Air Force Office of Scientific Research, the National Science Foundation, the Defense Threat Reduction Agency, and the Department of Energy, Lin’s group worked with one of the most common halide configurations, which is formed from methylammonium, lead, and bromide.
Their process involves first forming star-shaped plastic molecules that could serve as “nanoreactors” by growing 21 polymer arms on a simple sugar molecule. Then, once precursor chemicals for the silica and perovskite nanocrystals are loaded onto the plastic molecule, several stages of chemical reactions produce the final system.
After the star-shaped plastic has played its role as a nanoreactor, the star-shaped components remain permanently attached, almost like hair, to the silica, which encases the perovskite. The 'hairs' then serve as the first layer of protection, repelling water and preventing the nanocrystals from clumping together. The subsequent layer of silica adds further protection should any water get past the water-repelling plastic hair.
“Synthesis and applications of perovskite nanocrystals have been a rapidly evolving research field over the past five years,” said Yanjie He, a co-author of the paper and former graduate student at Georgia Tech. “Our strategy, based on a judiciously designed star-shaped plastic as a nanoreactor, enables unprecedented control in the crafting of high-quality perovskite nanocrystals with complex architecture, which is inaccessible in conventional approaches.”
To test the material, the researchers coated glass substrates with a thin film of the encapsulated perovskites and conducted several stress tests, including immersing the entire sample in deionized water. By shining ultraviolet light upon the sample, they found that the photoluminescent properties of the perovskites never diminished during a 30-minute test. For comparison, the researchers also immersed unencapsulated perovskites in water and watched as their photoluminescence vanished in a matter of seconds.
Lin said the new method unlocks the possibility of tuning the surface characteristics of the dual-shelled nanocrystal to enhance its performance in a greater range of applications. The process of fabricating the new perovskite nanocrystals from the star-shaped plastic was also unique in that it employed low-boiling point solvents with low toxicity. Future research may center on developing different perovskite nanocrystal systems, including all-inorganic perovskites, double perovskites, and doped perovskites.
“We envision that this type of perovskite nanocrystal will prove very useful for creating durable optoelectronic devices for bioimaging, biosensors, photonic sensors, and radiation detection, as well as next generation LEDs, lasers, and scintillators,” Lin said. “This is because these hairy perovskite nanocrystals carry unique advantages, including high defect tolerance, narrower emission bands, and high scintillation efficiency.”