Scientists at the Helmholtz-Zentrum Berlin have improved a process for vertically depositing a solution made from an inexpensive perovskite solute onto a moving substrate placed below. Not only have they discovered the crucial role played by one of the solvents used, but they have also taken a closer look at the aging and storage properties of the solution.

Process schematic for slot die coating perovskite inks imageThe liquid solution of perovskite precursor, solvent, and additive flows from a slit-shaped nozzle onto the glass substrate being conveyed below. Credit: Jinzhao Li / HZB

The perovskite solar cells that Prof. Eva Unger and her team at the Helmholtz-Zentrum Berlin (HZB) are researching seem to be extremely promising. “These are the best solar cells to date that can be made using a 2D ink”, the researcher explains. “And now their efficiencies are approaching those for cells made of crystalline silicon.”

Many methods have been developed and used to fabricate small test cells in the laboratory, where they can be studied and improved. However, industrial-scale fabrication is yet to be achieved. Unger knows from her own experience: “Unfortunately, processes that are optimized for fabricating small surface areas cannot always be scaled up.” In other words: Not everything that works perfectly in the lab also necessarily works economically on the factory floor. “That's why we are taking the next step and developing scalable methods. This means our team is focussing on processes for coating larger surfaces.” At the Hybrid Silicon Perovskite Research, Integration & Novel Technologies (HySPRINT) Innovation Lab, an infrastructure for collaboration between HZB and industry, the team is concentrating on processes that have already proven their importance in industry to start with.

“We have experimented here with slot-die coating”, she explains. In this process, the “ink”, as the thin liquid solution of perovskite precursor, solvent, and additive is known in the trade, flows from a slit-shaped nozzle and falls like a curtain onto the glass substrate being conveyed below that will later become a solar cell. After application, crystallization begins. An ultra-thin layer of a semiconducting perovskite structure grows. Unger, together with her team members doctoral student Jinzhao Li and Dr. Janardan Dagar, have now discovered that the exact amount of an organic solvent called dimethyl sulfoxide (DMSO) in the material ink is critical for this process. Unger uses it as an additive because it has an amazing effect on the ink. “DMSO induces crystallization nuclei for the perovskite”, says the researcher. Crystallization nuclei usually are tiny grains that help jump-start a crystal and promote its growth. “During X-ray diffraction experiments at BESSY II, we saw quite a big difference between inks with and without DMSO added”, the chemist explains.

However, as her team has found out in many experiments, the amount added plays a decisive role here. More DMSO favours crystal growth – up to a certain point. If this is exceeded, other processes come into play and the resulting microstructure reduces the performance of the solar cells. “It's like seasoning a soup”, says Unger. “If you add too little, it remains bland. If you add too much, it won't taste good either. So you need to add just the right amount to make it best.” In addition to the optimal composition, the HZB team has also thoroughly investigated the ageing processes and thus the storage life of the inks. “This is an aspect that has received little attention so far”, Unger explains. “The age of a perovskite precursor ink can influence device performance. This is an important factor that must be considered when developing inks and processes.”