A team of researchers from Mahidol University, Chiang Mai University and PERCH-SIS Institute in Thailand has developed a new precision spray-coating method that enables more complex perovskite solar cell designs and could be scaled up for mass production.
The researchers demonstrated the technique by depositing a perovskite material with higher stability on different perovskite material with better electrical properties. Applying different perovskite materials in each layer can be used to customize a device’s properties or meet specific performance and stability requirements.
“Our work demonstrates a process to deposit perovskite layer by layer with controllable thicknesses and rates of deposition for each layer,” said research team leader Pongsakorn Kanjanaboos from the School of Materials Science and Innovation, Faculty of Science, Mahidol University in Thailand. “This new method enables stacked designs for solar cells with better performance and stability.”
One of the advantages of perovskites are that they are solution processable, meaning that a solar cell is made by drying liquid perovskite into a solid at a low temperature. This fabrication process is much easier and less expensive than making a traditional silicon solar cell, a process that requires very high temperatures and cutting a solid material into wafers.
However, the solution process typically used to make perovskites does not allow multilayer designs because the upper layer tends to dissolve the already-dried lower layer. To overcome this challenge, the researchers turned to a process known as sequential spray deposition in which tiny droplets of a material are applied to a surface.
After trying different spray coating methods, they found one that worked at temperatures around 100 °C. They then optimized the spray parameters to ensure that the tiny droplets dried and crystalized into solid perovskite immediately upon contact with the already-dried lower layer.
“With our spray coating process, the solution of the upper layer doesn’t disturb the solid film making up the first layer,” said Pongsakorn. “Endless combinations of stacked perovskite architectures with any number of layers can be designed and created with precise control of thicknesses and rates of deposition for each layer.”
The researchers plan to use the new approach to make multilayer perovskite devices with new functions and combinations of performance and stability that were not possible before.