The University of Macau (UM) Institute of Applied Physics and Materials Engineering (IAPME) and Nanjing Tech University jointly developed a method to prepare phase-pure quasi two-dimensional (2D) metal-halide perovskites, which could be used for constructing stable perovskite solar cells.
The very low formation energy of the typically used three-dimensional (3D) perovskites accounts for their low stability and hinders the commercialization of perovskite optoelectronic devices. Recent studies show that the dimensionality of deposited perovskites could be reduced from 3D to quasi 2D by introducing an appropriate amount of long organic cations into the precursor solution, which can greatly improve the stability of perovskites thanks to the protection offered by the organic cation layer on the surface. However, such 2D perovskites typically consist of multiple quantum wells with a random well width distribution because of the thermodynamic stability of compounds in the solution. The thick quantum wells and 3D perovskite within the deposited film will still limit the overall stability of the material. Therefore, the deposition of phase-pure quasi 2D perovskite remains a key scientific challenge.
To address this challenge, Dr. Liang Chao at the IAPME, in collaboration with researchers from Nanjing Tech University, has developed a method to prepare phase pure quasi 2D perovskite. They overcame the traditional constrains by probing perovskite crystallization processes and tailoring the ionic coordination between different components. Based on these phase-pure 2D perovskites, they have successfully constructed solar cells with high stability and efficiency.