Researchers develop novel accelerated aging testing method and a perovskite solar cell with a commercially viable lifetime

Researchers from Princeton University in the U.S and Sweden's Linköping University have reported the development of "the first perovskite solar cell with a commercially viable lifetime". The team estimates their device can perform above industry standards for around 30 years, far more than the 20 years used as a threshold for viability for solar cells.

Not only is the device said to be highly durable, but it also meets common efficiency standards. It is the first of its kind to rival the performance of silicon-based cells, which have been market leaders for decades. 

The Princeton team, led by Princeton's Lynn Loo, said the record-setting design has highlighted the durable potential of PSCs, especially as a way to push solar cell technology beyond the limits of silicon. But she also pointed past the headline result to her team’s new accelerated aging technique as the work’s deeper significance. “We might have the record today,” she said, “but someone else is going to come along with a better record tomorrow. The really exciting thing is that we now have a way to test these devices and know how they will perform in the long term.”

Due to perovskites’ well-known frailty, long-term testing hasn’t been much of a concern until now. But as the devices get better and last longer, testing one design against another will become crucial in rolling out durable, consumer-friendly technologies.

“This paper is likely going to be a prototype for anyone looking to analyze performance at the intersection of efficiency and stability,” said Joseph Berry, a senior fellow at the National Renewable Energy Laboratory who specializes in the physics of solar cells and who was not involved in this study. “By producing a prototype to study stability, and showing what can be extrapolated [through accelerated testing], it’s doing the work everyone wants to see before we start field testing at scale. It allows you to project in a way that’s really impressive.”

While efficiency has accelerated at a remarkable pace over the past decade, Berry said, the stability of these devices has improved more slowly. For them to become widespread and rolled out by industry, testing will need to become more sophisticated. That’s where Loo’s accelerated aging process comes in.

“These kinds of tests are going to be increasingly important,” Loo said. “You can make the most efficient solar cells, but it won’t matter if they aren’t stable.”

Xiaoming Zhao, a postdoctoral researcher in Loo’s lab in the Andlinger Center for Energy and the Environment, had been working on a number of designs with colleagues. The efforts layered different materials in order to optimize light absorption while protecting the most fragile areas from exposure. They developed an ultra-thin capping layer between two crucial components: the absorbing perovskite layer and a charge-carrying layer made from cupric salt and other substances. The goal was to keep the perovskite semiconductor from burning out in a matter of weeks or months, the norm at that time.

This capping layer is extremely thin; Scientists use the term 2D to describe it, meaning two dimensions, as in something that has virtually no thickness at all. In reality, it’s merely a few atoms thick — more than a million times smaller than the smallest thing a human eye can see. While the idea of a 2D capping layer isn’t new, it is still considered a promising, emerging technique. Scientists at NREL have shown that 2D layers can greatly improve long-haul performance, but no one had developed a device that pushed perovskites anywhere close to the commercial threshold of a 20-year lifetime.

Zhao and his colleagues went through many permutations of these designs, shifting minute details in the geometry, varying the number of layers, and trying out dozens of material combinations. Each design went into the light box, where they could irradiate the sensitive devices in relentless bright light and measure their drop in performance over time.

In the fall of that year, as the first wave of the pandemic subsided and researchers returned to their labs to tend to their experiments in carefully coordinated shifts, Zhao noticed something odd in the data. One set of the devices still seemed to be operating near its peak efficiency.

“There was basically zero drop after nearly half a year,” he said. That’s when he realized he needed a way to stress test his device faster than his real-time experiment allowed. “The lifetime we want is about 30 years, but you can’t take 30 years to test your device,” Zhao said. “So we need some way to predict this lifetime within a reasonable timeframe. That’s why this accelerated aging is very important.”

The new testing method speeds up the aging process by illuminating the device while blasting it with heat. This process speeds up what would happen naturally over years of regular exposure. The researchers chose four aging temperatures and measured results across these four different data streams, from the baseline temperature of a typical summer day to an extreme of Fahrenheit, higher than the boiling point of water.

They then extrapolated from the combined data and forecast the device’s performance at room temperature over tens of thousands of hours of continuous illumination. The results showed a device that would perform above 80 percent of its peak efficiency under continuous illumination for at least five years at an average temperature of 95 degrees Fahrenheit. Using standard conversion metrics, Loo said that’s the lab equivalent of 30 years of outdoor operation in an area like Princeton, NJ.

Berry of NREL concurred. “It’s very credible,” he said. “Some people are still going to want to see it play out. But this is much more credible science than a lot of other attempts at forecasting.”

Posted: Jun 17,2022 by Roni Peleg