Researchers from Korea's Institute for Basic Science (IBS), Chinese Academy of Sciences, the University of Rochester in the U.S, and The Australian National University have increased the photoresponsivity of a lead-halide perovskite for solar cell applications by 250%. They created a perovskite film with a plasmonic substrate made of hyperbolic metamaterial and characterized it with transition dipole orientation.
The team has considerably reduced electron recombination processes in lead-halide perovskites (LHPs) used for solar cell applications. Recombination can have a significant impact on electrical performance in perovskite cells, with implications for open-circuit voltage, short-circuit current, fill factor, and ultimately, power conversion efficiency.
The scientists used what they call a “physics-based method” to create a film based on a type of LHP known as methylammonium lead iodide (MAPbI3). They deposited that directly on a plasmonic substrate made of hyperbolic metamaterial (HMM) with a high local density of state, via spin coating. They fabricated the multi-layered HMM with four pairs of alternative 10 nm thick layers made of silver, aluminum sulfate, and ozone (Ag-Al2 O3) by electron beam evaporation.
“The metal layer serves as a mirror, which creates reversed images of electron-hole pairs, weakening the ability of the electrons to recombine with the holes,” the scientists said, noting that they used a momentum-resolved imaging technique to characterize the film's transition dipole orientation, which is the key factor enabling control over exciton recombination processes.
They claim that the interaction between the in–plane dipole of the LHP and its image formed on plasmonic substrate results in a tenfold decrease in the recombination rate, without any chemical treatment, optical cavity, and photonic band–gap engineering.
“Furthermore, image dipole interaction enables us to substantially improve the device performance of photodetectors by achieving more than 250% increase in the photoresponsivity,” they added.