University of Toledo team reports breakthrough in new material for all perovskite tandem solar cells

Researchers from the University of Toledo have reported progress that may push the performance of tandem perovskite solar cells to new levels. Working in collaboration with the U.S. Department of Energy's National Renewable Energy Lab and the University of Colorado, Dr. Yanfa Yan, UToledo professor of physics, envisions that the new high efficiency tandem perovskite solar cell will be ready to debut in full-sized solar panels in the consumer market in the near future.

"We are producing higher-efficiency, lower-cost solar cells that show great promise to help solve the world energy crisis," Yan said. "The meaningful work will help protect our planet for our children and future generations. We have a problem consuming most of the fossil energies right now, and our collaborative team is focused on refining our innovative way to clean up the mess."

The new research paper outlines how the photovoltaics team is fine-tuning a mix of lead and tin to advance the technology closer to its maximum efficiency. Efforts have currently brought the efficiency of the new solar cell to about 23 percent. In comparison, silicon solar panels on the market today have around an 18 percent efficiency rating.

The scientists used a chemical compound called guanidinium thiocyanate to dramatically improve the structural and optoelectronic properties of the lead-tin mixed perovskite films.

About five years ago Yan's team at UToledo identified the ideal properties of perovskites and he has since focused his 20 years of experience on producing an all-perovskite tandem solar cell that brings together two different solar cells to increase the total electrical power generated by using two different parts of the sun's spectrum.

Last month the U.S. Department of Energy awarded Yan a $1.1 million grant to continue his research in collaboration with the National Renewable Energy Lab. "This is the material we've been waiting for for a long time," Yan said. "The solar industry is watching and waiting. Some have already started investing in this technology."

"Our UToledo research is ongoing to make cheaper and more efficient solar cells that could rival and even outperform the prevailing silicon photovoltaic technology," said Dr. Zhaoning Song, research assistant professor in the UToledo Department of Physics and Astronomy and co-author on the study. "Our tandem solar cells with two layers of perovskites deliver high power conversion efficiency and have the potential to bring down production costs of solar panels, which is an important advance in photovoltaics."

While Yan's team has improved the quality of the materials and the process to manufacture them at a low cost, more progress needs to be made.

"The material cost is low and the fabrication cost is low, but the lifetime of the material is still an unknown," Song said. "We need to continue to increase efficiency and stability."

"Also, lead is considered a toxic substance," Yan said. "I am determined to work with the solar industry to ensure solar panels made of this material can be recycled so they don't cause harm to the environment."

Posted: May 15,2019 by Roni Peleg