Perovskite Solar
What are perovskite?
Perovskites are a class of materials that share a similar structure, which display a myriad of exciting properties like superconductivity, magnetoresistance and more. These easily synthesized materials are considered the future of solar cells, as their distinctive structure makes them perfect for enabling low-cost, efficient photovoltaics. They are also predicted to play a role in next-gen electric vehicle batteries, sensors, lasers and much more.
How does the PV market look today?
In general, Photovoltaic (PV) technologies can be viewed as divided into two main categories: wafer-based PV (also called 1st generation PVs) and thin-film cell PVs. Traditional crystalline silicon (c-Si) cells (both single crystalline silicon and multi-crystalline silicon) and gallium arsenide (GaAs) cells belong to the wafer-based PVs, with c-Si cells dominating the current PV market (about 90% market share) and GaAs exhibiting the highest efficiency.
Thin-film cells normally absorb light more efficiently than silicon, allowing the use of extremely thin films. Cadmium telluride (CdTe) technology has been successfully commercialized, with more than 20% cell efficiency and 17.5% module efficiency record and such cells currently hold about 5% of the total market. Other commercial thin-film technologies include hydrogenated amorphous silicon (a-Si:H) and copper indium gallium (di)selenide (CIGS) cells, taking approximately 2% market share each today. Copper zinc tin sulphide technology has been under R&D for years and will probably require some time until actual commercialization.
What is a perovskite solar cell?
An emerging thin-film PV class is being formed, also called 3rd generation PVs, which refers to PVs using technologies that have the potential to overcome current efficiency and performance limits or are based on novel materials. This 3rd generation of PVs includes DSSC, organic photovoltaic (OPV), quantum dot (QD) PV and perovskite PV.
A perovskite solar cell is a type of solar cell which includes a perovskite structured compound, most commonly a hybrid organic-inorganic lead or tin halide-based material, as the light-harvesting active layer. Perovskite materials such as methylammonium lead halides are cheap to produce and relatively simple to manufacture. Perovskites possess intrinsic properties like broad absorption spectrum, fast charge separation, long transport distance of electrons and holes, long carrier separation lifetime, and more, that make them very promising materials for solid-state solar cells.
Perovskite solar cells are, without a doubt, the rising star in the field of photovoltaics. They are causing excitement within the solar power industry with their ability to absorb light across almost all visible wavelengths, exceptional power conversion efficiencies already exceeding 20% in the lab, and relative ease of fabrication. Perovskite solar cells still face several challenge, but much work is put into facing them and some companies, are already talking about commercializing them in the near future.
What are the advantages of Perovskite solar cells?
Put simply, perovskite solar cells aim to increase the efficiency and lower the cost of solar energy. Perovskite PVs indeed hold promise for high efficiencies, as well as low potential material & reduced processing costs. A big advantage perovskite PVs have over conventional solar technology is that they can react to various different wavelengths of light, which lets them convert more of the sunlight that reaches them into electricity.
Moreover, they offer flexibility, semi-transparency, tailored form factors, light-weight and more. Naturally, electronics designers and researchers are certain that such characteristics will open up many more applications for solar cells.
What is holding perovskite PVs back?
Despite its great potential, perovskite solar cell technology is still in the early stages of commercialization compared with other mature solar technologies as there are a number of concerns remaining.
One problem is their overall cost (for several reasons, mainly since currently the most common electrode material in perovskite solar cells is gold), and another is that cheaper perovskite solar cells have a short lifespan. Perovskite PVs also deteriorate rapidly in the presence of moisture and the decay products attack metal electrodes. Heavy encapsulation to protect perovskite can add to the cell cost and weight. Scaling up is another issue - reported high efficiency ratings have been achieved using small cells, which is great for lab testing, but too small to be used in an actual solar panel.
A major issue is toxicity - a substance called PbI is one of the breakdown products of perovskite. This is known to be toxic and there are concerns that it may be carcinogenic (although this is still an unproven point). Also, many perovskite cells use lead, a massive pollutant. Researchers are constantly seeking substitutions, and have already made working cells using tin instead. (with efficiency at only 6%, but improvements will surely follow).
What’s next?
While major challenges indeed exist, perovskite solar cells are still touted as the PV technology of the future, and much development work and research are put into making this a reality. Scientists and companies are working towards increasing efficiency and stability, prolonging lifetime and replacing toxic materials with safer ones. Researchers are also looking at the benefits of combining perovskites with other technologies, like silicon for example, to create what is referred to as “tandem cells”.
Commercial activity in the field of perovskite PV
In September 2015, Australia-based organic PV and perovskite solar cell (PSC) developer Dyesol declared a major breakthrough in perovskite stability for solar applications. Dyesol claims to have made a significant breakthrough on small perovskite solar cells, with “meaningful numbers” of 10% efficient strip cells exhibiting less than 10% relative degradation when exposed to continuous light soaking for over 1000 hours. Dyesol was also awarded a $0.5 million grant from the Australian Renewable Energy Agency (ARENA) to commercialize an innovative, very high efficiency perovskite solar cell.
Also in 2015, Saule Technologies signed an investment deal with Hideo Sawada, a Japanese investment company. Saule aims to combine perovskite solar cells with other currently available products, and this investment agreement came only a year after the company was launched.
In October 2020, Saule launched sunbreaker lamellas equipped with perovskite solar cells. The product is planned to soon be marketed across across Europe and potentially go global after that.
In August 2020, reports out of China suggested that a perovskite photovoltaic cell production line has gone into production in Quzhou, east China's Zhejiang Province. The 40-hectare factory was reportedly funded by Microquanta Semiconductor and expected to produce more than 200,000 square meters of photovoltaic glass before the end of 2020.
In September 2020, Oxford PV's Professor Henry Snaith stated that the Company's perovskite-based solar cells are scheduled to go on sale next year, probably by mid 2021. These will be perovskite solar cells integrated with standard silicon solar cells.
Germany’s national metrology institute uses WAVELABS equipment to improve solar measurement capabilities and prepare for testing PSCs
The Physikalisch-Technische Bundesanstalt (PTB), Germany’s national metrology institute, has modernized its solar module calibration system, achieving a measurement uncertainty of just 0.9%—currently the lowest known uncertainty for a power measurement of silicon solar modules under standard test conditions worldwide.
This achievement was made possible by a new setup based on an LED solar simulator developed by WAVELABS.
Researchers explore the combined effect of 2D-3D perovskite layers on the performance of PSCs
Researchers from India's Madan Mohan Malaviya University of Technology, University of Delhi, Manipal University and Sweden's IAAM have combined 2D and 3D perovskites to strengthen both reliability and efficiency of 3D perovskite solar cells (PSCs).
The team explored the combined effect of Dion-Jacobson (DJ) 2D-3D halide-based perovskites layers on device performance. The DJ 2D material used was PeDAMA4Pb5I16, while the 3D material is the lead-free, stable CsGeI3-xBrx (with x=1). The optimized solar cell structure developed in this work consisted of (Au/Cu2O/PeDAMA4Pb5I16/CsGeI3-xBrx/PCBM/FTO).
Selenophene-modified ETLs can improve inverted perovskite solar cells
Researchers from Spain's UPV/EHU, ICIQ-BIST, CIDETEC and Mexico's Instituto Politécnico Nacional have explored the effect of chalcogen substitutions in fullerene derivatives to enhance efficiency and stability of perovskite solar cells.
The team examined the effects of chalcogen substitution in the chemical structure of phenyl-butyric acid methyl ester (PCBM) on the performance and stability of inverted perovskite solar cells (PSCs). PCBMs are the most widely used electron transport materials in inverted PSCs. However, these compounds can suffer from lack of stability under irradiation. In the race for optimizing the PCBM-like derivatives, the thiophene moiety has garnered significant attention for enhancing the performance and stability of PSCs. The novelty in this study relies on the tests done on the selenophene derivative. This compound was compared to thiophene and furan substituted derivatives, and to the reference PCBM without a chalcogenophene moiety, demonstrating a better surface passivation and reduced interfacial charge recombination.
Researchers report improved carbon-based perovskite solar cells through treatment with neostigmine bromide
Carbon-based all-inorganic perovskite solar cells (C-PSCs) are known for their inexpensive manufacturing process. However, their perovskite constituents are susceptible to the formation of numerous structural defects and halide vacancies, which can induce substantial energy level misalignments between the light-absorbing layer and the carbon electrode. This discrepancy hinders the extraction and transfer of holes, thereby adversely affecting the overall efficiency of the device.
Image credit: Chemical Engineering Journal
Researchers from China's Huaqiao University have proposed an interfacial post-treatment strategy aimed at reinforcing perovskite layers through the application of Neostigmine bromide (NMB) as a modifier. The team employed NMB to treat the upper interface of the perovskite, addressing intrinsic phase segregation, passivating surface defects, and filling halogen vacancies, thereby enhancing the photoelectric performance and stability of the device.
Multifunctional sulfur-based additives could improve perovskite solar cells' efficiency and moisture stability
Aiming to explore the potential of sulfur-based additives for increasing both device power conversion efficiency and moisture stability of perovskite solar cells, researchers from BCMaterials (Spain), Huazhong University of Science and Technology (China), Max Planck Institute for Polymer Research (Germany) and CNRS (France) have reported a mechanism for the local nanoscopic humidity ingression into a multifunctional additiviated formamidinium-loaded halide perovskites.
a) The molecular structure of additives used. Image from: Advanced Energy Materials
By tuning the iodide and bromide tails of the additives, the influence of sulfur heteroatom containing ammonium-amidinium salts on the photo-physical and device properties of a formamidinium-rich perovskite absorber was uncovered.
SEI Energy Technology announces successful trial production of perovskite modules in China-based production line
SEI Energy Technology (Jiaxing), a joint venture in China between Solaires Enterprises (Victoria BC, Canada) and Genesis Technologies (Shanghai), has announced the successful trial production of its perovskite modules from its mass production line. The companies view the success of this trial production as a significant breakthrough that demonstrates the potential of this production line, that lays a foundation for the large-scale commercialization of perovskite materials and solar modules.
Solaires is focused on research and application development in the field of indoor light power generation. Its third party tested conversion efficiency reportedly exceeded 35% in 2024. In addition, SEI’s manufacturing process of perovskite materials is relatively simple, which can greatly shorten the production cycle and improve production yield. The raw materials used are environmentally friendly and have significant cost advantages.
Researchers develop efficient ultrathin perovskite solar cell featuring a silver-backed mirror
Researchers from the Chinese Academy of Sciences (CAS), ShanghaiTech University, Zhejiang Laboratory and Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering recently reported an efficient (>27% reported efficiency) perovskite solar cell that uses a back mirror based on silver to improve light harvesting.
The ultrathin perovskite solar cell utilizes a Gires-Tournois resonator to improve light absorption - an optical standing-wave resonator designed for generating chromatic dispersion. Gires-Tournois resonators are usually based on a reflective metal mirror and are primarily used in chirping applications such as pulse compression. The structure of the resonator in this study had a simple optical structure, combined with a silver back mirror, to optimize light capture and utilization while improving light absorption capacity.
China revises PV industry standards
China aims to encourage companies to focus on innovation, quality and production costs. As part of this effort, it was reported that China's Ministry of Industry and Information Technology (MIIT) has announced revisions to its photovoltaic manufacturing industry standards, addressing current challenges like businesses' repetitive expansion of low-level production capacity and falling profitability, to promote the PV industry's healthy development.
The MIIT has also raised the efficiency standards for new monocrystalline silicon PV cells and modules, and the revised standards also address next-generation technologies such as perovskite modules, with conversion efficiency requirements set at a minimum of 14% for existing projects and 15.5% for new projects.
We interview Sofab Inks' CEO & COO, discussing the company's materials, business, and industry outlook
Sofab Inks develops and produces advanced materials for perovskite solar cells. The company's flagship product is a solvent-based tin oxide ETL that has already seen promising results in improving the performance and lifespan of perovskite solar cells. We interviewed the company's CEO Blake Martin and COO Jack Manzella, who help us understand the company's materials and business better. Click here to contact Sofab Inks to learn more or request a material sample.
Hello Blake and Jack. Earlier this year, Sofab Inks launched Tinfab, a high-performance and low-cost ETL material for perovskite solar cells. Can you detail the market reaction for your new material, and also the performance benefits that one can expect from this new ETL?
Since launching Tinfab, we’ve experienced significant interest across the industry, with approximately 40 companies and universities currently testing the material in perovskite solar cell applications. This strong engagement underscores the market's demand for innovative, scalable ETL solutions.
Tinfab is designed to fully replace C60/fullerenes in perovskite solar cells, addressing key limitations of C60, including lower stability, higher costs, and the complexity of vacuum deposition. Unlike C60, Tinfab can be solution-deposited in ambient environments, making it far more suitable for scalable manufacturing.
Japan to step up perovskite solar cell use by 2040
Japan's industry ministry is reportedly promoting the use of perovskite solar cells to cover 20 gigawatts of electricity — the equivalent of 20 nuclear reactors — in 2040, officials said. The plan is part of work to expand the use of renewable energy sources by supporting the introduction of next-generation technologies as the country is racing to reduce carbon emissions.
A perovskite solar cell by Toshiba. Image credit: Toshiba
The ministry aims to include the plan in the country's basic energy program that the government will update within fiscal 2024, which ends next March. The existing energy program calls for increasing the proportion of renewable energy sources to 36% to 38% of power generation in fiscal 2030, compared with 22.9% in fiscal 2023. The new program, which sets goals for fiscal 2040, is expected to further raise the renewable energy share in anticipation of the spread of perovskite solar cells.
