Researchers develop high-performance flexible 2D perovskite solar cells using a novel DEA spacer cation
Researchers from China's Shenzhen University of Information Technology, Handan Polytechnic College and Harbin Institute of Technology have developed a new strategy to improve the performance of two-dimensional (2D) perovskite solar cells by introducing diethylammonium (DEA⁺) as a spacer cation, addressing the long-standing trade-off between stability and efficiency in these materials.
2D perovskites are seen as a promising alternative to their 3D counterparts due to their enhanced environmental stability, which originates from the incorporation of bulky organic spacer cations between inorganic layers. These spacers act as barriers against moisture and oxygen ingress, but they typically introduce insulating characteristics that hinder charge transport and reduce crystallinity. As a result, while 2D perovskites have achieved power conversion efficiencies (PCEs) up to 19.41%, further improvements are constrained by limited carrier mobility and suboptimal film quality. In this work, the researchers replaced the commonly used phenylethylammonium (PEA⁺) spacer with DEA⁺ in layered perovskite structures of the form A'₂MAₙ₋₁PbₙI₃ₙ₊₁, focusing on the n = 4 composition (DEA₂MA₃Pb₄I₁₃). Structural characterization revealed a substantial improvement in film morphology: DEA-based films exhibited grain sizes of approximately 1.5 μm, compared to less than 150 nm for PEA-based films. This increase in grain size is indicative of reduced grain boundary density, which directly lowers trap-assisted recombination and facilitates more efficient carrier transport.

