Researchers develop copper-doped perovskite catalysts for on-demand hydrogen production from methanol
Researchers at Austria's Montanuniversitat Leoben and TU Wien have developed copper-doped perovskite-type oxide catalysts that improve the efficiency and durability of methanol steam reforming (MSR), a process used to generate hydrogen on demand for fuel cells. The catalysts require significantly less active copper than conventional industrial catalysts while operating at comparatively low temperatures with high hydrogen yield.
Methanol is gaining attention as a hydrogen carrier because it can be stored and transported as a liquid, is chemically stable at ambient pressure, and can be produced from renewable sources such as biomass or captured CO2 combined with green hydrogen. Steam reforming releases the hydrogen bound in methanol, offering a route to decentralized, on-demand hydrogen production without extensive infrastructure - useful for portable fuel cells and small-scale refueling stations. Conventional Cu/ZnO/Al2O3 catalysts used for MSR, however, suffer from thermal instability, sintering and side reactions that reduce selectivity and durability over time.