Researchers at Taizhou University in China, led by corresponding authors Yanxian Jin, Guiqiang Pu, and Jiacheng Wang of the Zhejiang Key Laboratory for Island Green Energy and New Materials, together with contributing researchers from the Chinese University of Hong Kong and the University at Buffalo, State University of New York, have developed a nickel-doping strategy for cesium lead bromide (CsPbBr3) perovskite nanocrystals that simultaneously improves scintillation brightness and environmental stability, two properties that have historically traded off against each other in halide perovskite scintillator materials.
(a) Schematic illustration of the introduction of Ni2+ into the lattice of CsPbBr3, effectively suppressing vacancy formation. (b) The effect of Ni2+ doping on defects and lattice in CsPbBr3. The Ni2+ doping could remove the defects and shrink the lattice. (c) The satellite map of PLQY, LY, stability for both CsPbBr3 and CsPbBr3:Ni. Image from: Nano Research
Metal halide perovskites such as CsPbBr3 are attracting growing interest as scintillators, materials that convert high-energy X-ray radiation into visible light for security screening, industrial inspection, and medical imaging, thanks to their high effective atomic number, strong optoelectronic performance, and low-cost solution processing relative to conventional inorganic scintillators like bismuth germanate (BGO) and CsI:Tl. Their practical deployment has been held back, though, by intrinsic structural instability and defect-driven nonradiative recombination that saps light output. Earlier metal-doping approaches using ions such as Mn2+ or Zn2+ have generally optimized only a single property at a time, and some, including Mn2+, introduce longer-lived luminescent centers that cause afterglow and blur continuous X-ray images.