Ecole polytechnique fédérale de Lausanne (EPFL)

Researchers at EPFL's Laboratory for Molecular Engineering of Optoelectronic Nanomaterials (LIMNO) and the University of Bern have designed an organic spacer molecule that turns the normally optically inactive layer of a 2D perovskite into a light-absorbing part of the device itself.

Layered "2D" perovskites are built from alternating organic and inorganic layers and are valued for their improved environmental stability and suppressed ion migration compared to standard 3D perovskites. However, the organic spacer molecules conventionally used to separate the inorganic layers, such as phenethylammonium (PEA), neither absorb sunlight nor conduct charge well, which limits both light harvesting and device performance. The team addressed this by building a spacer cation around a diketopyrrolopyrrole (DPP) core, an organic semiconductor known for strong absorption deep into the visible spectrum. By systematically tuning the length of the alkyl chain linking the DPP core, the researchers found that a dihexyl-substituted version was the right size to form an ordered layered perovskite structure, denoted (DPP-dH)PbI₄, while shorter linkers produced only disordered, amorphous material.

Researchers from the Hong Kong Polytechnic University (PolyU), École Polytechnique Fédérale de Lausanne (EPFL), Wenzhou Institute of Technology (WIT), University of Nottingham Ningbo China, Shenzhen University of Advanced Technology, North China Electric Power University, Zhejiang University, Peking University and the University of Oxford have developed an advanced AI-robotics framework that redefines how perovskite solar cells (PSCs) are synthesized, fabricated, and analyzed. 

The study introduces a domain-specific recipe language model (RLM) integrated with 11 interconnected robotic boxes to achieve fully enclosed, automated, and feedback-driven experimentation for PSC research. At the heart of this system lies a seven-layer artificial intelligence (AI) architecture encompassing learning, generating, RecipeQA, fine-tuning, reasoning, evaluation, and optimization. This structure allows both numerical and semantic recipes - formulas and parameters derived from over 60,000 PSC-related studies - to be encoded into machine-readable formats, optimized by the language model, and translated into robotic instructions. Each robotic box contributes to a closed-loop workflow that connects recipe recommendation, fabrication, characterization, and semantic mechanistic analysis.

An international team of researchers, including ones from Iritaly Trading Company, École Polytechnique Fédérale de Lausanne (EPFL), University of Rome Tor Vergata, Argonne National Laboratory and Italy-based Greatcell Solar, has reported a co-crystal engineering approach to improve the long-term stability of perovskite solar cells and modules.

The team used a neutral molecule, benzoguanamine, as a linker in low-dimensional perovskites, replacing conventional ionic molecules, to form a co-crystal. By applying this co-crystal layer onto the perovskite layer, they achieved power conversion efficiency of 23.4% in small-area solar cells, and 23.1% and 18.5% on solar modules with active areas of 9.0 cm² and 48 cm², respectively. The solar modules retained more than 95% and 98% of their initial efficiency after >5,000 h of 1-sun light soaking and >1,000 h of ultraviolet-ray exposure, respectively, at maximum power point conditions. They also retained more than 91% of their initial efficiency after >5,000 h of continuous thermal stress at 85 °C.

Researchers from China's Southeast University, Henan University and Xiamen University, Germany's HZB, Switzerland's EPFL, Imperial College London, Queen Mary University of London, and Cardiff University in the UK and Italy's University of Cagliari have developed an interfacial engineering strategy that significantly enhances both the power conversion efficiency and operational stability of metal halide perovskite solar cells.

Metal halide perovskite photovoltaics exhibit outstanding optoelectronic properties, including high absorption coefficients and long carrier diffusion lengths, yet their long-term reliability remains a principal barrier to industrial deployment. To address this limitation, the international team introduced sodium heptafluorobutyrate (SHF) as a multifunctional interfacial modifier positioned between the perovskite absorber and the fullerene-based electron-selective contact (C60).

Researchers from EPFL, Northwestern University, University of Toronto, Kaunas University of Technology and Toin University of Yokohama recently achieved one of the highest efficiencies ever reported for fully inorganic perovskite solar cells. They also demonstrated for the first time that these cells can operate stably for hundreds of hours, approaching the reliability of commercial silicon solar cells.

Long-term stability is essential for commercialization of perovskite technology. One of the most important methods for reducing defects and protecting the surface from external factors is passivation. This process makes the perovskite surface more resistant to temperature, humidity, and other environmental conditions, thereby extending the device’s lifetime. “Passivation makes the perovskite surface chemically inactive, eliminating the defects introduced during production,” explains Dr. Kasparas Rakštys, from the Faculty of Chemistry at Kaunas University of Technology (KTU) in Lithuania.