Flexibility

This is a sponsored post by Ergis Group

In 2020, Poland-based Ergis Group launched the noDiffusion film platform, a high-barrier film that offers high level of optical transmittance and low level of light scattering, and the ability to contain transparent conductive electrodes. The new technologies adopted in the production of the barrier films offer a combination of high performance and competitive pricing.

Following years of R&D, Ergis is ready to enter production with its first-gen barrier films, produced using sputtering in a roll-to-roll (R2R) configuration. The company reports performance of around 10^-4 wtr performance for its barrier. This is referred to as a "light-barrier" and one that is more than enough for the encapsulation of perovskite materials. The company collaborated with Poland-based Saule Technologies to develop this specific film. Ergis is now shipping barrier film samples to its customers.

It was reported that Sekisui Chemical, a Japanese plastics maker, will begin mass production of perovskite solar cells (PSCs) in an effort to catch up with Chinese competitors.

The company will invest more than 10 billion yen (over USD $68 million) to build a new manufacturing facility with an annual production volume of several hundred thousand square meters by 2030.

A collaborative effort by researchers from the Centre for Hybrid and Organic Solar Energy (CHOSE), Department of Electronic Engineering at Tor Vergata University of Rome, Italy, the Department of Textile Engineering at the University of Guilan, Iran, GreatCell Solar Italia, Institute of Crystallography (IC-CNR), Italy, Department of Biological and Environmental Sciences and Technologies at the University of Salento, Italy and Institute of Nanotechnology (CNR NANOTEC), Italy, has resulted in the development of flexible perovskite solar cells with remarkable power conversion efficiencies (PCE) under white LED illumination.

The team achieved a maximum PCE of 28.9% at an illuminance of 200 lx and a record of 32.5% at 1000 lx, essentially converting a third of the incoming power (note that under 1 sun this figure for perovskite technology is less, i.e. one quarter).

India-based P3C Technology and Solutions has announced a fund raise of $250,000 with a further commitment of $3 million based on successful trails. The funds will be used to demonstrate the flexible perovskite solar cells to various government and private bodies like Indian Railway and automobile manufacturers. 

According to P3C, the investment comes from Oberoi Thermit Private Limited, a company with an impressive history of introducing new and innovative products and services which are highly beneficial for Railways. The organization is always looking to introduce new and improved technologies in India which can benefit the country. They are responsible for the introduction of some of the most safety critical technologies in Indian Railways like 3D Scanning of Bridge bed, Bridge Health Monitoring, Vehicular Ultrasonic Testing of rails, Phased Array Ultrasonic Testing of welds amongst other things. 

Researchers at University of Rome “Tor Vergata”'s CHOSE (Centre for Hybrid and Organic Solar Energy) and CNR-ISM Institute of Structure of Matter have deposited flexible perovskite solar modules without using toxic solvents, via blade coating in ambient air. 14% PCE was reportedly obtained through the optimization of coating parameters and the use of additives. 

The scalable ambient air deposition of perovskite solar devices remains a major challenge of this technology. In addition, toxic solvents are regularly used in perovskite layer deposition, which can damage the environment and endanger the safety of potential production lines. In this recent work, the team managed to address these issues and fabricate sustainable flexible perovskite solar modules (flex-PSMs), in which all layers were deposited via a blade coating in ambient air without the usage of toxic solvents. 

Researchers from Saule Research Institute, Saule Technologies, Centre for Hybrid and Organic Solar Energy (CHOSE), CNR-SCITEC, Istituto Italiano di Tecnologia (IIT), Wroclaw University of Science and Technology, Bydgoszcz University of Science and Technology and Poznan University of Technology have demonstrated an effective strategy to improve the technical aspects of flexible perovskite solar cells,  improving the reliability and efficiency values of these devices.

The team applies large organic ammonium molecules for modifying a buried interface between a hole-transporting layer (HTL) and perovskite-absorbing material. With the 4-fluorophenethylammonium iodide (FPEAI), they achieved 18.66% efficiency for the large-area (1 cm²) flexible solar cell, a significant improvement over the pristine device without modification.

Researchers at CSIRO and Monash University have reported a flexible perovskite solar cell manufactured using roll-to-roll compatible “printing” type processes, which could potentially be used in large-scale manufacturing. To achieve this, the team developed a viable roll-to-roll process to deposit the electrode layer, which has thus far been a major challenge. The team managed to fabricated cells which achieved a maximum efficiency of 16.7%.

Photo: Hasitha Weerasinghe/CSIRO

Roll-to-roll processes signify a potential for low-cost manufacturing of flexible perovskites. However, adding the electrode layer in a process compatible with the roll-to-roll setup has proven to be a challenge. The research team in this recent work set out to address this issue and develop a process that could allow the electrode layer to be deposited without the need for solvents or heat treatments that potentially damage the perovskite layer as well.

Researchers from Sungkyunkwan University (SKKU), Korea University, Seoul National University and Korea's Frontier Energy Solution have demonstrated the feasibility of using the van der Waals stacking (vdWS) strategy to overcome the inefficiencies of flexible perovskite solar cells (f-PSCs).

The team explained that using halide perovskites can significantly increase the power conversion efficiency (PCE) of f-PSCs due to the low-temperature processability, ultrathin dimensions, low weight, and excellent optoelectronic properties of such cells. Several efforts were also made to develop the charge transporting layer (CTL), interface engineering between CTLs and perovskite, and highly-crystalline perovskite films on a flexible substrate, which further increased the f-PSC PCE to 22.44%. However, the efficiency is only 87% of the conventional glass-based PSCs. The f-PSC efficiency is affected by the physical process limitations caused by the flexible substrates' flexibility. Polymer substrates, such as polyethylene naphthalate (PEN) or polyethylene terephthalate (PET), or tin-doped indium oxide (ITO) are typically used as flexible substrates for f-PSCs.

A group of scientists, led by Prof. Yiqiang Zhan from Fudan University, has reported high-efficiency flexible perovskite solar cells (f-PSCs) by annealing a SnO₂ ETL in a rough vacuum at a low temperature (100 '), and peak efficiency reached 20.14%.

SnO₂ layers that have been prepared by this method have shown higher robustness and hydrophobicity in comparison with samples prepared in an air atmosphere and temperatures of 100 °C, leading to an improved ETL/perovskite interface connection and reducing defects in the SnO₂/perovskite interface. The appropriate density of oxygen vacancies on the surface during this treatment can be responsible for higher conductivity, which is beneficial for charge transfer.

An international team of researchers, including ones from Brown University, EPFL, Dalian University of Technology and Shaanxi Normal University, has developed a flexible thin-film perovskite solar cell with an efficiency of 21.0%.

The perovskite layer for the cell, which has an “n-i-p” layout, was fabricated using a metal-halide capping layer placed on top of a three-dimensional metal-halide perovskite film. This design reportedly provides hermetically sealed encapsulation, which is traditionally difficult to achieve in flexible perovskite cells, and also enhances the photocarrier properties at the interface between the perovskite film and the hole transport layer (HTL).