Hybrids and related materials - Page 3

Scientists from Japan's Gifu University and the Tokyo Institute of Technology have identified a chalcogenide perovskite material with light absorption attributes strong enough to offer the potential for a theoretical maximum conversion efficiency of 38.7% in a silicon perovskite tandem solar cell.

The material ' BaZrTiS₃ ' has a light absorption coefficient exceeding 10⁵cm^-1, the highest of all solar cell materials including chalcogenide perovskites such as SrZrS₃, BaHfS₃ and SrHfS₃, the scientists claim.

The groups of Steve Albrecht and Bernd Stannowski at HZB have reached a record efficiency of 29.15% of its tandem solar cell made of perovskite and silicon.

The illustration shows the structure of the tandem solar cell: between the thin perovskite layer (black) and the silicon layer (blue) are functional intermediate layers. © Eike Köhnen/HZB

This value has been officially certified by the CalLab of the Fraunhofer Institute for Solar Energy Systems (ISE) and means that surpassing the 30% efficiency mark is now within reach.

In September 2019, a research team led by Prof. Steve Albrecht from the HZB (in close collaboration with Kaunas University of Technology in Lithuania) announced a tandem solar cell with certified efficiency of 23.26% that combines the semiconducting materials perovskite and CIGS. Now, the team shares further details on these cells and states that an unnamed Japanese manufacturer has acquired the rights to produce them.

The scientists said the self-assembling material used for the cell is made of molecules based on carbazole head groups with phosphonic acid anchoring groups, and consists of 1-2nm of self-assembled monolayers deposited on the surface of the perovskite by dipping it into a diluted solution.

A Cornell-led team of scientists has discovered a crystalline material with ultralow thermal conductivity, which could lead to the design of novel energy conversion materials and devices.

After studying a popular hybrid perovskite and identifying the mechanisms for its low thermal conductivity, Zhiting Tian, assistant professor of mechanical and aerospace engineering at Cornell, turned her attention to a hybrid perovskite analogue, methylammonium bismuth iodide (CH₃NH₃)₃Bi₂I₉, which she hypothesized would have an even lower thermal conductivity because of the unique disconnected structure of its inorganic molecules.

An international team of researchers, including ones from Penn State, Columbia University, University of Toledo, Northeastern University in the U.S and Carl von Ossietzky University in Germany, designed next-gen solar cells that mimic photosynthesis with a biological material, by adding the protein bacteriorhodopsin (bR) to perovskite solar cells.

Power conversion efficiency (PCE) distribution of bR-incorporated PSC based on statistics of 15 devices, with average efficiency of 16.34 %. Image from ACS article

'These findings open the door for the development of a cheaper, more environmentally friendly bioperovskite solar cell technology,' said Shashank Priya, associate vice president for research and professor of materials science at Penn State. 'In the future, we may essentially replace some expensive chemicals inside solar cells with relatively cheaper natural materials.'

Researchers at the University of Rome Tor Vergata in Italy and Russia's NUST MISIS institute have investigated how cells containing two-dimensional titanium-carbide MXene support layers could improve perovskite solar cell performance.

To obtain good power conversion within a perovskite solar cell, all layers and layer interfaces within the cell must have good compatibility. Typical cells contain the active perovskite material sandwiched between two charge transport layers, which are then adjacent to their corresponding electrodes. Support layers may also be added. Charge mobility, energy barriers, interface energy alignment, and interfacial vacancies all impact compatibility and subsequent cell performance and stability. Thus, engineering well-suited interfaces with the cell is paramount to cell success and long-term stability, an important criterion for potential commercialization.

Researchers from the Ulsan Institute of Science and Technology (UNIST) have demonstrated a new method of fabricating perovskite-on-silicon tandem devices, using a transparent conductive adhesive (TCA) to combine the two cells. The scientists have developed devices with demonstrated efficiencies of 19.4%, and propose methods to bring that up to over 24% using existing technology.

While the efficiency is still well below the 28% record for a perovskite/silicon tandem cell set by Oxford PV, the UNIST group says its method is far simpler to manufacture than previous concepts. 'It is meaningful to develop an attached tandem solar cell unlike the conventional tandem solar cell with stacked structure,' said UNIST's In Young Choi, lead author of the study. 'We have observed that the TCA effectively connects the different light-absorbing layers.'

A team led by Prof. Steve Albrecht from the HZB has announced a new world-record: a tandem solar cell with certified efficiency of 23.26% that combines the semiconducting materials perovskite and CIGS. One reason for this success lies in the cell's intermediate layer of organic molecules: they self-organize to cover even rough semiconductor surfaces. Two patents have been filed for these layers.

Perovskite-based solar cells have experienced an incredibly rapid increase in efficiency over the last ten years. The combination of perovskites with classical semiconductor materials such as silicon and copper-indium-gallium-selenide (CIGS) compounds in tandem solar cells promises low-cost, high-performance solar modules for the future. However, losses at the electrodes between the two semiconductors considerably reduce the efficiency.

Solliance and U.S-based MiaSolé announced a new record - power conversion efficiency of 23% on a flexible tandem solar cell: a top flexible semi-transparent perovskite solar cell with a bottom flexible copper indium gallium selenide (CIGS) cell.

This achievement comes only 9 months after the January 2019 announcement by Solliance and MiaSolé regarding a flexible solar cell with an impressive power conversion efficiency of 21.5%. The solar cell, similarly to this newly announced one, combined two thin-film solar cell technologies into a 4 terminal tandem solar cell stack: a top flexible semi-transparent perovskite solar cell with a bottom flexible copper indium gallium selenide (CIGS) cell.

German university the Karlsruhe Institute of Technology (KIT), the Center for Solar Energy and Hydrogen Research Baden-Würtetemburg (ZSW) and CIGS module manufacturer Nice Solar Energy have announced an ambition to design tandem PV modules based on CIGS and perovskite, which can theoretically achieve efficiencies well above 30%.

The joint 'Capitano' project will run for three years and has received more than €5 million from Germany's Federal Ministry for Economic Affairs and Energy. The aim of the project is to develop cells with stable higher efficiencies, which can be interconnected to form efficient tandem solar modules.