Perovskite applications

A research team at the Fraunhofer Institute for Solar Energy Systems ISE has reported a perovskite/perovskite/silicon triple-junction solar cell with an open circuit voltage of >2.8 V, which is said to be the record value reported for this structure so far. The Fraunhofer team showed that perovskite-perovskite-silicon subcells can hold considerable promise and have an even greater efficiency potential than double-junction tandem cells.

The triple-junction solar cell was developed as part of the Triumph research project funded by the European Commission and the RIESEN research project funded by the German Federal Ministry for Economic Affairs and Climate Action. This achievement confirms that the cell has excellent material properties for generating electricity, leading the scientists to deduce that it has an efficient solar cell architecture.

Researchers from Pohang University of Science and Technology (POSTECH), Chinese Academy of Sciences (CAS) and University of Electronic Science and Technology of China have developed perovskite transistors through the use of three distinct perovskite cation processes. 

The team showed that pure-tin perovskite thin-film transistors can be created using triple A cations of caesium–formamidinium–phenethylammonium. This approach reportedly leads to high-quality cascaded tin perovskite channel films with low-defect, phase-pure perovskite/dielectric interfaces.

Researchers from Japan's Tohoku University and University of Tsukuba have reported a breakthrough in the development of non-volatile phase change memory−a type of electronic memory that can store data even when the power is turned off−using a perovskite-derivative nickelate material.

Until now, phase change memory has primarily been developed using chalcogenides, a group of materials known to exhibit reversible electrical changes when they transition between their crystalline and amorphous states. However, in their recent study, the researchers reported thermally reversible switching of room-temperature electrical resistivity in a layered nickelate−potentially offering better performance and superior sustainability.

Researchers from Linköping University in Sweden and Universidad de Concepción in Chile recently designed a new type of random number generator for encryption, based on Perovskiye LEDs. The new technology could make digital information exchange safer, cheaper and more environmentally friendly and even pave the way for a new type of quantum communication.

To encrypt information, a random number generator is used, which can either be a computer program or the hardware itself. The random number generator provides keys that are used to both encrypt and unlock the information at the receiving end. Different types of random number generators provide different levels of randomness and thus security. Hardware is the safer option as randomness is controlled by physical processes. And the hardware method that provides the best randomness is based on quantum phenomena – what researchers call the Quantum Random Number Generator, QRNG.

Researchers from Japan's Tokyo Institute of Technology, University of Oxford in the UK and Colorado State University in the U.S have shown that α-FAPbI₃, a promising solar cell material with a cubic perovskite structure that is metastable at room temperature, can be stabilized by introducing a pseudo-halide ion like thiocyanate (SCN^–) into its structure. The recent findings provide new insights into the stabilization of the α-phase via grain boundary and pseudo-halide engineering.

A material with good photophysical properties that has recently gained momentum is α-formamidinium lead iodide or α-FAPbI₃ (where FA⁺ = CH(NH₂)₂⁺), a crystalline solid with a cubic perovskite structure. Solar cells made of α-FAPbI₃ exhibit a remarkable 25.8% conversion efficiency and an energy gap of 1.48 eV. Unfortunately, α-FAPbI₃ is metastable at room temperature and undergoes a phase transition to δ-FAPbI₃ when triggered by water or light. The energy gap of δ-FAPbI₃ is much larger than the ideal value for solar cell applications, making the preservation of the α-phase crucial for practical purposes. To overcome this problem, the team of researchers, led by Associate Professor Takafumi Yamamoto from Tokyo Institute of Technology (Tokyo Tech), has recently presented a new strategy for stabilizing α-FAPbI₃.

According to reports, Panasonic is planning to sell windows made of “power-generating glass”, with perovskite solar cells integrated into transparent panes, to deliver power for homes. The module reportedly has a conversion efficacy of 17.9%, which is said to be the second highest worldwide for a perovskite cell larger than 800 sq. centimeters, ( after China’s UtmoLight - 18.6%).

Panasonic has been developing the cells since 2014 but only recently completed a test project, which consisted of installing the innovative glass on the balcony of a model home in its smart-town project in Kanagawa prefecture.

Researchers from The University of Sydney, University of New South Wales, Macquarie University and University of Technology Sydney have demonstrated efficient perovskite solar cells (PSCs) on steel substrates.

The team explained that steel, being flexible and conductive, can itself can act as both a substrate and an electrode for either large-area-monolithic-panel or smaller-area-singular single-junction or multi-junction cell fabrication. The reported cells could be used for building-integrated PV (BIPV), vehicle-integrated solar (VIPV), or other design-integrated photovoltaics for terrestrial or space applications.

It was reported that Sekisui Chemical, a Japanese plastics maker, will begin mass production of perovskite solar cells (PSCs) in an effort to catch up with Chinese competitors.

The company will invest more than 10 billion yen (over USD $68 million) to build a new manufacturing facility with an annual production volume of several hundred thousand square meters by 2030.

Researchers from Chonnam National University, Chinese Academy of Sciences,  Indian Institute of Science (IISc) and Pennsylvania State University have introduced an alternative solar cell design fully based on inorganic perovskites. Their solar cells could be easier to fabricate on a large-scale, while also achieving promising power conversion efficiencies (PCEs).

The key objective of the recent work was to create new solar cells fully based on inorganic perovskites using a developed method that could be easy to up-scale. Ultimately, they fabricated their solar cells using hot-air and thermal evaporation deposition techniques that work at ambient conditions without requiring polar solvents (i.e., liquids containing both positive and negative charges).

Researchers from Harvard University have reported a bioinspired liquid-based encapsulation strategy, that offers protection from water without sacrificing the operational properties of the encapsulated materials.

Using halide perovskite as a model system, the team showed that damage to the perovskite from exposure to water is drastically reduced when it is coated by a polymer matrix with infused hydrophobic oil.