Melting hybrid organic–inorganic perovskite results in a new family of glasses

Researchers from the University of Cambridge, University of Liverpool, CNRS, Indian Association for the Cultivation of Science and Diamond Light Source have shown the by melting and quenching hybrid organic'inorganic perovskite compounds, it is possible to create a new family of glasses that could find uses in the energy sector.

Comparison of physical properties of melt-quenched glasses with various materials imageComparison of physical properties of melt-quenched glasses with various materials. Image from study

The research team made three hybrid organic'inorganic perovskite compounds based on tetrapropylammonium with manganese(II), iron(II) and cobalt(II) and melted them. According to author François-Xavier Coudert at the CNRS in France, they had to tune the temperature to aim for a very narrow temperature window, around 20 degrees on average, depending on each metal used ' hot enough to liquefy the samples, but not so hot that it decomposes them. The team measured the exact heat coming in and out of the glasses to learn their properties, describing each one thoroughly. 'We're melting a novel class of materials and accessing a novel family of glasses,' Coudert says. 'I've probably never seen materials so well characterized with so many techniques and so much information. It is fascinating to see all of these methods together.'

'A chemist making something is very good, but knowing and understanding what you've made, is even more exciting,' adds co-author Frédéric Blanc, a researcher at the University of Liverpool. 'This is often the key challenge for amorphous materials.'

The team compared the new glasses' physical properties against other materials like silica. The new glasses have extremely low thermal conductivity and moderate electrical conductivity at room temperature, meaning they are suitable for thermoelectric applications. 'We are highly hopeful toward its industrial applications in waste heat energy recovery systems, power generation systems, renewable and clean energy, among others,' says first author Bikash Shaw, a researcher at the University of Cambridge, UK. 'We could potentially try to substitute current thermoelectric materials, which contain heavy and environmentally unsuitable elements, with our recently discovered glasses,' he adds.

Kavassery Narayan, a physicist at the Jawaharlal Nehru Centre for Advanced Scientific Research, who isn't involved in the study, said this about the work: 'The fact that they can use a metal'oxide framework based on hybrid perovskite and then make it amorphous by melting and rapidly cooling is an important development. The glassy nature opens up many applications in electrical conductivity and thermal conductivity.'

Coudert adds that it would be interesting to use this detailed knowledge of the glasses' structure to play around with its components. 'Since [the glasses] are organic'inorganic hybrids, we could tune the different components. We could change properties from material to material by using this 'Lego principle', where we change the bricks and obtain different properties. I don't think this is about having a material that beats everything else right now, but it's more like allowing us to see a future where things can be controlled, tuned and improved,' he says.

Posted: Jun 02,2021 by Roni Peleg