Solid oxide fuel cells, or SOFCs, are a type of electrochemical device that generates electricity using hydrogen as fuel, with the only 'waste' product being water.
To potentially accelerate the development of more efficient SOFCs, a research team from Kyushu University, Yamagata University and Kyushu Synchrotron Light Research Center has uncovered the chemical innerworkings of a perovskite-based electrolyte developed for SOFCs. The team combined synchrotron radiation analysis, large-scale simulations, machine learning, and thermogravimetric analysis, to uncover the active site of where hydrogen atoms are introduced within the perovskite lattice in its process to produce energy.
At the fundamental level, a fuel cell is a device that generates electricity by facilitating the split of a hydrogen atom into its positively charged proton and negatively charged electron. The electron is used to generate electricity, and then comes together with a proton and oxygen and produces water as a 'waste' product. The material at the center of all this is the electrolyte. This material acts as an atomic sieve that facilitates transfer of specific atoms across the fuel cell. Depending on the type of fuel cell, those atoms could be protons or oxygen.
SOFC technology has already been commercialized in a rather limited scale, as they remain expensive, with one of the largest obstacles being their high operating temperature. "Conventional SOFCs need to be at 700-1000℃ for the electrolyte to perform efficiently," explains Professor Yoshihiro Yamazaki at Kyushu University's Platform of Inter-/Transdisciplinary Energy Research, who led the research. "Naturally, there's a global race to develop SOFC electrolytes that can operate at lower temperatures of around 300-450℃. One such promising materials are perovskites."
"In our past work we developed a Barium and Zirconium based perovskite with the chemical composition BaZrO3. By replacing the Zr site with a high concentration of Scandium, or Sc, we succeeded in making a high-performance electrolyte that can function at our target temperature of 400℃," explains Yamazaki. "Of course, that was only a part of what we wanted to find. We also were investigating a question that hadn't been solved for over three decades: where in the electrolyte's lattice do the protons get introduced?"
Probing the inner workings of SOFCs had been difficult due to its high operating temperature and changing pressure from water, the fuel cell's source of hydrogen.
To get around these issues, the team conducted X-ray absorption spectroscopy experiments on their perovskite electrolyte using synchrotron radiation—the electromagnetic radiation emitted from particle accelerators—while the fuel cell was active at around 400℃.
"These results gave us insight into where in the material's chemical structure the protons would be incorporated. From there we applied machine learning, and using a supercomputer calculated possible structural configurations of the material," continued Yamazaki. "By carefully comparing the predicted results with experimental data we were able to clarify the structural changes the electrolyte undertakes when active."
"Now that we have the fundamental innerworkings of the electrolyte we can being optimizing its nanostructures and even propose new materials that can lead to more efficient fuel cells, and even ones that work at wider temperature ranges," concludes Yamazaki.