New vapor-based fabrication strategy enables 16.36% efficient lead-free perovskite indoor solar cells
Researchers at the University of Queensland and Southwest University have developed a vapor-based fabrication strategy for lead-free tin-based halide perovskite (THP) indoor solar cells, addressing challenges in crystallization control while achieving high efficiency under low-light conditions.
A central challenge in thermally evaporated THP films is their complex and poorly controlled crystallization kinetics, which often leads to defects and performance losses. To overcome this, the team introduced formamidine acetate (FAAc) as a vapor-deposited additive during the formation of FASnI2Br films. FAAc coordinates with SnI2 to form a metastable SnI2-FAAc intermediate phase. This intermediate slows and regulates the solid-state reaction pathway, allowing more controlled crystal growth. At the same time, FAAc reduces the surface free energy of the underlying SnI2 layer, enabling more uniform deposition of the subsequent FABr layer. This dual effect - kinetic regulation and improved film wetting - results in higher-quality perovskite films with fewer defects and significantly suppressed trap-assisted recombination.

