Researchers use ultrathin polymer membrane for improved hole extraction and ion blocking in perovskite solar cells
Researchers from Huaqiao University, City University of Hong Kong and Chinese Academy of Sciences (CAS) have explained that highly efficient perovskite solar cells in the n-i-p structure demonstrated limited operational lifetimes earlier due to the layer-to-layer ion diffusion in perovskite/doped hole-transport layer (HTL) heterojunction, leading to conductivity drop in HTL and component loss in perovskites. Now, they have reached 26.39% efficiency of perovskite solar cells using an ultrathin (~7 nm) p-type polymeric interlayer (D18) with excellent ion-blocking ability between perovskite and HTL to address these issues.
Device architecture, the structure of D18 polymer, and the detailed ion blocking effect of D18 membrane. Image credit: Nature Communications
The ultrathin D18 interlayer effectively inhibits the layer-to-layer diffusion of lithium, methylammonium, formamidium, and iodide ions. Additionally, D18 improves the energy-level alignment at the perovskite/HTL interface and facilitates efficient hole extraction.