Researchers study the origin of the photovoltaic effect in organic–inorganic perovskites

A team led by RIKEN researchers recently investigated how certain perovskite materials convert light into electricity. Their findings could hel improve their efficiency and use in solar cells.

Solar cells convert light into electricity by a phenomenon known as the photovoltaic effect. The vast majority of solar cells consist of two semiconductors put together—one with an excess of electrons and the other being electron deficient. This is because the setup has a high conversion efficiency. But another photovoltaic effect has also been attracting attention—the bulk photovoltaic effect, so called because it only involves a single material. While its conversion efficiency is currently rather low, recent research has suggested ways for improving its efficiency.


Scientists are still learning how the bulk photovoltaic effect works. It was originally thought that an electric field generated by polarizations within the material gave rise to the effect, but a new explanation has recently been gaining traction. In this new mechanism, light shifts the electron clouds in the material and these shifts propagate, generating a current. This current has attractive properties, including an ultrafast response and dissipation-less propagation.

Organic–inorganic hybrid perovskites (OIHPs) have great potential for making optoelectronic devices. The bulk photovoltaic effect in OIHPs has generally been ascribed to the old macroscopic polarization mechanism.

“Built-in electric fields in materials have often been considered as the origin of the bulk photovoltaic effect in OIHPs, but without solid evidence”, said Taishi Noma of the RIKEN Center for Emergent Matter Science.

Now, by studying the bulk photovoltaic effect in OIHP crystals, Noma and his collaborators have found evidence that is consistent with the shift mechanism and rules out the macroscopic polarization mechanism.

Specifically, they observed the bulk photovoltaic effect along a non-polar axis in an OIHP, which cannot be explained in terms of the macroscopic polarization mechanism.

The team’s results highlight the importance of the crystal symmetry of the material. The insights gained could help researchers optimize the properties of OIHPs by tailoring their symmetry. In particular, the insights may help improve the efficiency of OIHPs in converting light into electricity.

Noma and his team now intend to explore other kinds of materials. “In principle, shift currents can also be generated in other classes of materials, such as liquid crystals and organic molecular crystals,” says Noma. “We would like to extend this study to other materials.”

Posted: Dec 26,2023 by Roni Peleg