Researchers track the movement of ions in perovskites to achieve better PSC stability

Researchers at Argonne National Laboratory and Purdue University recently reported an effort to prevent perovskite solar cell degradation by tracking the movement of ions in perovskites. 

The team used X-rays at the Advanced Photon Source and a custom-built characterization platform to reveal the way ions move within different perovskite crystals under ultraviolet radiation (UV). Scientists are interested in testing material stability under UV because it can significantly degrade solar cell performance, sometimes by more than 50%, after extended exposure.


Electricity is harvested from light when it collides with a solar cell, knocking electrons out of their bonds and allowing them to circulate and move around. However, instability in perovskites means that iodine, for example, leaves the system as iodine gas, creating a vacancy for ions to migrate towards, causing defects that make the system cease functioning. Researchers hope to improve perovskite stability to achieve a solar cell lifetime of twenty to thirty years, making them more useful to industry.

“Perovskite has a lot of potential for solar cells, and also for use in LED displays. At Argonne, we hope to use the powerful X-ray beams to decode perovskites’ mysteries and uncover potential pathways to conquer their stability hurdles,” said Argonne materials scientist Yanqi (Grace) Luo, the lead author on the paper.

To enhance perovskite solar energy conversion, scientists improve material stability through innovative compositions and structural engineering. By altering halide ratios adding these ions in varying sizes or amounts, scientists can change favorably perovskites’ nature and use.

Since the light-harvesting characteristics of hybrid perovskites are unstable and easily altered, extra care and a specially designed scientific setup were required to study them. Some microscopes can record only a snapshot, providing a certain set of information about a sample at the instant of measurement. Instruments at the APS can record and provide data on conditions of the sample during the entire observation, meaning researchers studying nanoscience can witness changes as they occur.

Luo’s team has shown that by using a technique called nanoprobe X-ray fluorescence (nano-XRF), they can directly capture the movement of halide atoms in perovskite materials before damaging them.

“This is a new platform to see precisely, at the nanoscale, what happens when the experimental materials are in operation,” said Argonne physicist Luxi Li, another author of the study.

The perovskite samples used by the team were lab-created low-dimensional or 2D materials. They consist of thin sheet of perovskites that are neatly sandwiched between two layers of bulky organic molecules. The researchers first performed nano-XRF measurements on the 2D crystals by collecting high-resolution elemental maps of atoms inside the materials. Then the researchers shined the same nano-focused X-ray probe to measure the atomic structure via X-ray absorption spectroscopy (XAS). The nano-XRF and XAS captured the halide redistribution and structural reduction in these 2D crystals under continuous UV irradiation, respectively. These findings provide new insights into understanding the degradation mechanisms in these material systems.

With the newly constructed XRF platform, the researchers added a few specialized optics and sensors that allowed them to carefully adjust the brightness of light and detect X-ray-excited optical photons during scans. The results indicated that lower dimensional perovskites show a clear link between stability and dimensionality. Substituting certain elements of the material and protecting the material with sheets of organic molecules provide a potential route to increase the stability of perovskite-based photovoltaics.

Currently, Luo and her team are exploring other approaches to limit the degree of halide redistribution to enhance material stability. And when the APS upgrade is complete, researchers like Luo and Li will be ready to hit perovskites with even more powerful x-rays. “With the APS Upgrade coming up, it should allow us to better understand the behavior and working principles in energy materials on various time scales,” Luo said.

The upgraded APS is expected to be online by spring 2024, at which time the APS will feature X-ray beams that are up to 500 times brighter. 

Posted: Jan 25,2024 by Roni Peleg