Researchers develop method for non-laser, all-vapor-phase processed perovskite solar modules stabilized by naturally formed barrier layers

Researchers at HZB's HySPRINT Innovation Lab, China's Tianjin University of Technology and Tianjin Institute of Power Sources have developed a non-laser additive method for manufacturing perovskite solar modules, in which an adjustable wire mask (AWM) was used to form the channels that were traditionally scribed by lasers. 

When module channels are made by conventional laser scribing, the heat-sensitive perovskite materials decompose, and the decomposition of perovskites in the open channel leads to reduced module stability. The electrode corrosion caused by the direct contact between the exposed perovskites and the metal electrode significantly increases the series resistance of the module. In this recent work, the team developed a non-laser additive method for manufacturing perovskite solar modules, in which an adjustable wire mask (AWM) was used to form the channels that were traditionally scribed by lasers. This method for making modules prevents contact between perovskites and electrodes. All layers, including perovskites, hole/electron transporting, and passivating and electrode layers, were fabricated via vapor-phase deposition, and by tuning the precursor composition, a power conversion efficiency (PCE) of 21.7% was obtained (0.1 cm2). 

 

A geometrical fill factor (GFF) of 98% was achieved via the method, even higher than most laser-processed perovskite solar modules, and thanks to the naturally formed barrier layers, the module (PCE of 18.4% and effective area of 12 cm2) showed good stability, retaining 90% of its efficiency after 500 h. 

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Posted: Mar 03,2024 by Roni Peleg