Researchers fine-tune the use of C60 ETLs for better perovskite solar cell technology

Researchers from King Abdullah University of Science and Technology (KAUST), Princeton University, Marmara University, Academy of Sciences of the Czech Republic and Nano-C have designed a perovskite-silicon tandem solar cell with a top inverted perovskite cell relying on an electron transport layer (ETL) made of thermally evaporated buckminsterfullerene (C60).

In the “p-i-n” device structure, hole-selective contact p is at the bottom of intrinsic perovskite layer i with electron transport layer n at the top. Conventional halide perovskite cells have the same structure but reversed – a “n-i-p” layout. In n-i-p architecture, the solar cell is illuminated through the electron-transport layer (ETL) side; in the p-i-n structure, it is illuminated through the hole‐transport layer (HTL) surface.


The team highlights the importance of process repeatability, crucial for commercialization. To this end, the team showed that for evaporated C60, which is the electron-selective contact material in high-efficiency tandems, such repeatability may be an issue, depending on the quality of the source material. The team also found that using sublimated C60 can resolve this issue.

In their recent paper, the research team explained that C60 is common as the preferred material for ETLs in inverted solar cells, due to its small conduction band offset and large valence band offset with respect to the perovskite absorber, which in turn is beneficial to the cell electron-extraction and hole-blocking properties.

The poor solubility of this material, however, requires the use of solution-based methods such as spin-coating, spray, or blade coating, although the preferred process to ensure minimizing parasitic optical absorption caused by C60 would be thermal evaporation.

The research group's findings reveal that, as a result of the heating and cooling cycles of the source material during multiple evaporation cycles, C60 undergoes a conversion into higher molecular weight structures through the fusion of C60 molecules. This transformation tends to lead to modifications in the electronic properties of the fullerene, detrimentally affecting device performance. However, the scientists also showed that further purification of as-received C60 can help to avoid these issues, and device performance remains unaffected even after repeated deposition cycles.

Through this process, the team fabricated a cell based on an indium tin oxide (ITO) substrate, a hole transport layer (HTL) made of nickel(II) oxide (NiOx) and phosphonic acid called methyl-substituted carbazole (Me-4PACz), a perovskite absorber, the C60 ETL, a bathocuproine (BCP) buffer layer, and a silver (Ag) metal contact.

This cell was then stacked as the top device in a perovskite-silicon tandem solar cell incorporating an anti-reflective coating based on magnesium fluoride (MgF2). Tested under standard illumination conditions, this tandem device achieved a power conversion efficiency of 30.90%, with the results being confirmed by Fraunhofer ISE CalLab.

The scientists believe these efficiency levels are encouraging and said commercial PV modules with C60 contacts are already in sight in the industry. Their work could provide valuable insights for the preparation of fullerenes that are more suitable, particularly oxygen-free, for commercial perovskite-based solar cell processing with high yield.

Posted: Jan 26,2024 by Roni Peleg